Here is a short Abstract regarding
relationship between Rheology and Acoustics.
Rheology and Acoustics are
two independents sciences that study influence of
mechanical stresses on solids and liquids. These
sciences merge on the same subject when stress
oscillates in time and wavelength of this
oscillation is much shorter than system size.
Description of stress-strain relationship under
these conditions would require notion of wave and
associated mathematical models. This link between
Rheology and Acoustics has been recognized long
time ago. We review these old papers in the
recently published paper mentioned on the left
column.
Rheology deals with two types of stresses
- shear and extensional. Both of them maintain
isochoric state of the system - liquid is
considered incompressible.
Acoustic, on the other hand, is associated
only with non-isochoric extensional stress. There
is a special term for such stress - longitudinal
stress. It is possible to introduce a "complex
longitudinal modulus" that describes visco-elastic
properties of a fluid under influence of
longitudinal stress. It is similar to the
traditional "complex shear modulus". Old
thermodynamic theories yield mathematical
equations that link both modules with penetration
depth, parameter that characterizes distance of
stress exponential decay. These equations are
identical for both modules. The only difference
between shear modulus (Rheology) and longitudinal
modulus (Acoustics) is penetration depth. It is
orders of magnitude larger for longitudinal stress
than for shear stress. This makes measurements
associated with longitudinal stress much simpler
at high frequency on MHz range.
We also
discuss two issues that present importance for
Rheology but are more known in Acoustics. The
first one is 160 years old Stokes's law for sound
attenuation in Newtonian fluid. Sound attenuation
is important for Rheology because it is reciprocal
to the penetration depth and, consequently,
determines longitudinal modulus. This law offers
also a simple way of testing Newtonian nature of a
fluid. We illustrate this experimentally with 12
different Newtonian liquids and two non-Newtonian
dispersions. Stokes's law offers also a way of
measuring "bulk viscosity" of Newtonian fluid.
This obscure parameter contains unique information
on fluid structure, molecular "rotational" and
"vibrational" degrees of freedom. We measure this
parameter, together with storage modulus and
compressibility for the same 12 Newtonian fluids
as mentioned above.
Acoustics makes possible
studying visco-elastic properties of complex
liquids at MHz range, which is not accessible for
traditional shear rheology. This makes it
complimentary tool for rheological studies.